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In his quest for a bride to break his immortal curse, a 939-year-old guardian of souls meets a grim reaper and a sprightly student with a tragic past.

When it comes to matters of the heart, Xiao Xiao believes she is something of an expert. The blogger behind a popular social media account which addresses all sorts of relationship issues, Xiao Xiao has no shortage of experience when it comes to love. However, all of her experiences online can’t prepare her for her first encounter with Lin Shen, a professional psychological counselor, who sees the world in an entirely different way. After butting heads on a popular variety show, Xiao Xiao hoped that she would never have to deal with Lin Shen ever again. But fate, it would seem, had other plans. Hoping to improve her ability to analyze emotional problems by learning from a true professional, Xiao Xiao applies for a position as a professional psychologist’s assistant. Only too late does she realize that the professional she’s working for is none other than the cold-hearted Lin Shen.

The Demon Headmaster is a British television series based on the children's books by Gillian Cross of the same name. Made for CBBC, the drama was first broadcast between 1996 and 1998. The first series contained six episodes, and aired twice weekly from 2 to 18 January 1996, the second series contained seven episodes, and aired once a week from 25 September to 6 November 1996, and the third series contained six episodes, and aired twice weekly from 6 to 22 January 1998. School location scenes in the first series were filmed at Hatch End High School, in Hatch End, Harrow, North West London and The Royal Masonic School for Girls in Rickmansworth, Hertfordshire. Other scenes were filmed around West London and the Vulcan Tower is in fact the Atrium building in Uxbridge. CGI was used to make this building appear on a traffic island close to Warwick Avenue tube station. Some scenes in the later series were filmed in the village of Sarratt, Hertfordshire and other locations in Hertfordshire and Buckinghamshire.